Dimethyl sulfoxide, DMSO, 99.0+%

CAS Number: 67-68-5

Linear Formula: (CH3)2SO

Molecular Weight: 78.13

IUPAC Name: Dimethyl sulfoxide

Other Names: Methanesulfinylmethane, Dimethyl(oxido)sulfur, Methylsulfinylmethane, Methyl sulfoxide

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Dimethyl sulfoxide (DMSO) is an organosulfur compound with the formula (CH3)2SO. This colorless liquid is an important polar aprotic solvent that dissolves both polar and nonpolar compounds and is miscible in a wide range of organic solvents as well as water. It has a relatively high melting point. DMSO has the unusual property that many individuals perceive a garlic-like taste in the mouth after contact with the skin.

In terms of chemical structure, the molecule has idealized Cs symmetry. It has a trigonal pyramidal molecular geometry consistent with other three-coordinate S(IV) compounds, with a nonbonded electron pair on the approximately tetrahedral sulfur atom.

DMSO is a polar aprotic solvent and is less toxic than other members of this class, such as dimethylformamide, dimethylacetamide, N-methyl-2-pyrrolidone, and HMPA. DMSO is frequently used as a solvent for chemical reactions involving salts, most notably Finkelstein reactions and other nucleophilic substitutions. It is also extensively used as an extractant in biochemistry and cell biology. Because DMSO is only weakly acidic, it tolerates relatively strong bases and as such has been extensively used in the study of carbanions. A set of non-aqueous pKa values (C-H, O-H, S-H and N-H acidities) for thousands of organic compounds have been determined in DMSO solution. Because of its high boiling point, 189 °C (372 °F), DMSO evaporates slowly at normal atmospheric pressure. Samples dissolved in DMSO cannot be as easily recovered compared to other solvents, as it is very difficult to remove all traces of DMSO by conventional rotary evaporation. One technique to fully recover samples is removal of the organic solvent by evaporation followed by addition of water (to dissolve DMSO) and cryodesiccation to remove both DMSO and water. Reactions conducted in DMSO are often diluted with water to precipitate or phase-separate products. The relatively high freezing point of DMSO, 18.5 °C (65.3 °F), means that at, or just below, room temperature it is a solid, which can limit its utility in some chemical processes (e.g. crystallization with cooling).

 
Data sheet
Chemical purity99.0+%
Molecular FormulaC2H6OS
Molecular Weight78.13

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Dimethyl sulfoxide, DMSO, 99.0+%

CAS Number: 67-68-5

Linear Formula: (CH3)2SO

Molecular Weight: 78.13

IUPAC Name: Dimethyl sulfoxide

Other Names: Methanesulfinylmethane, Dimethyl(oxido)sulfur, Methylsulfinylmethane, Methyl sulfoxide

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